What I’m understanding from your post is that you want to start using Linux as much as possible instead of Windows, so you’re looking for alternatives to the Windows apps that you’re accustomed to.
Have I understood correctly?
Regarding replacement programs, you’d need to check each one on its own.
The customary replacements for Windows Word and Excel are LibreOffice Writer and Calc respectively. However, there are incompatibilities. Because Word and Excel are closed, it’s not possible to make a fully-compatible system. If you need full compatibility, or as close to it as possible, either use Microsoft’s online 360 or look at OnlyOffice and FreeOffice. Or use Windows (whether in a VM or dual boot).
For games, Steam is by far the most popular and the most compatible, because Valve Corporation explicitly supports Linux. It’s not 100%, but I’m told that it’s close (I’m not a gamer, so I can’t speak from experience).
WINE is a system to try to get Windows apps to work on Linux. It works well for a few apps, partly for a few more apps, badly for yet more apps, and not at all for most apps. Don’t rely on it. If you wish to experiment, you’d be well advised to install Bottles instead (it’s available only on flatpak). Bottles is a front-end for WINE, which makes it far easier to use (because WINE is quite complicated).
You can view a list of compatible apps in the WineHQ database, split into ratings: Platinum, Gold, Silver, Bronze and Garbage. I avoid using WINE as much as possible; there is only one legacy Windows app that I use daily, and it would fit in the Silver section.
I only very occasionally use Windows. I log in once a week to run the updates, and whenever I need to look at it when I’m trying to support my father, who uses it. My Windows build is in VirtualBox.